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  • Graphene shows promise

    Researchers are looking for new materials that can take over where silicon will leave off.

    By Martin Rowe, Senior Technical Editor -- Test & Measurement World, 8/1/2010 12:00:00 AM

    Martin Rowe, Senior Technical Editor

    When you think of how far semiconductor devices—particularly CMOS—have come in terms of speed, it can leave you dumbstruck. One day, though, silicon-based ICs will reach their speed limits. Researchers are, therefore, looking for new materials that can take over where silicon will leave off. One such material is graphene. Still in the research stage, graphene is showing promise for applications such as high-speed transistors, sensors, super capacitors, and solar cells.

    Graphene sheet


    Graphene sheets form a single-atom layer on silicon or other materials. Courtesy of IBM.

    Graphene is carbon grown on substrates such as silicon, glass, and copper in layers that are just one atom thick. Thus, graphene sheets are two dimensional. The carbon atoms are arranged in hexagonal shape, like a honeycomb. When doped with impurities, graphene takes on some interesting properties.

    For example, electrons can pass right through a graphene sheet without knocking into other electrons—a phenomenon called "ballistic transport," which means the material has very low resistance. Lower resistance results in lower voltage losses, which could lead to a new range of low-power electronic devices.

    Graphene is being applied in the construction of RF transistors that could set new bandwidth records. IBM has announced the development of graphene transistors with a bandwidth of 100 MHz (Ref. 1). See links to papers on graphene research.

    At first, graphene MOSFET transistors wouldn't work in digital applications because the single-layer sheet has no band gap between a MOSFET's gate and its source-drain channel. Without a band gap, a transistor won't turn off (Ref. 2) and would function as an analog device only. In June, researchers at Lawrence Berkeley National Labs announced that they had created a two-layer graphene device. With two layers, the researchers made a device with a controlled band gap, from 0 meV to 250 meV (Ref. 3). With that band gap, graphene transistors could work as digital devices.


    To read past "Tech Trends" columns, go to www.tmworld.com/techtrends.

    View links to scientific papers on graphene-based devices.
    As a sensor, graphene could, with the proper doping, detect the presence of specific chemical compounds. It's also showing properties that make it light sensitive. Thus, graphene could find use in solar cells or as infrared detectors (Ref. 4).

    Super capacitors are yet another possible application for graphene. Experiments have shown that chemically modified graphene ranges in capacitance from 99 F/g to 135 F/g depending on the doping material. These values are high compared to dielectric capacitors but lower than batteries or fuel cells (Ref. 5).

    As researchers experiment with graphene-based devices, they must characterize them. That requires measurements. Mary Anne Tupta, senior applications engineer at Keithley Instruments, often assists researchers who, when characterizing graphene transistors, measure a device's I-V curves with source-measure units. Some researchers are measuring the characteristics of the graphene sheets themselves. They may put just 1 pA of current through a sheet and measure its resistance. Many of the papers listed below discuss how researchers make these measurements.


    References
    1. "Made in IBM Labs: IBM Scientists Demonstrate World's Fastest Graphene Transistor," IBM, February 5, 2010. www.ibm.com.
    2. Schwierz, Frank, "Graphene transistors," Nature Nanotechnology, published online May 30, 2010. www.nature.com/nnano.
    3. "Bilayer Graphene Gets a Bandgap," Berkeley Lab, June 10,2009. www.lbl.gov.
    4. Hwang, G., et al., "Graphene as Thin Film Infrared Optoelectronic Sensor," 2009 International Symposium on Optomechatronic Technologies. www.isir.upmc.fr/files/isot_09.pdf.
    5. Stoller, M.D., et al., "Graphene-Based Ultra­capacitors," American Chemical Society, Washington, DC, 2008. www.utexas.edu.

    USB test switch for PXI

    The Model 40-737 test switch from Pickering Interfaces lets you connect up to eight USB devices to a single PXI card. You can use the switch to automatically test USB peripherals. Each port's power is switched through software. www.pickeringtest.com.

    Videos on noise figure measurements

    Agilent Technologies has released a CD containing five videos called "Hints For Making Noise Figure Measurements." www.agilent.com.

    Reference CD on nanoscale measurements

    Keithley Instruments' "Nanotechnology Test Tutorials" CD contains technical papers, articles, and data sheets on how to make measurements on nanoscale semiconductor devices and carbon nanotubes. www.ggcomm/Keithley/Jun10_PR_NanoCD.html.

    Graphene resources

    The following links take you to scientific papers on graphene-based devices. The papers have been
    published by various scientific journals. (Links courtesy of Keithley Instruments.)

    Breakthrough In Energy Storage: New Carbon Material Shows Promise Of Storing Large Quantities Of Renewable Electrical Energy
    www.sciencedaily.com/releases/2008/09/080916143910.htm

    Compatibilizing Effect of Graphite Oxide in Graphene/PMMA Nanocomposites
    www.cheric.org/PDF/MMR/MR17/MR17-8-0626.pdf

    Conductivity engineering of graphene by defect formation
    adl.serveftp.org/papers/Conductivity%20engineering%20of%20graphene%20by%20defect%20
    formation.pdf


    Divergent resistance at the Dirac point in graphene: Evidence for a transition in a high magnetic field
    www.princeton.edu/~npo/Publications/publicatn_08-10/09DivergenceGraphenePRB.pdf

    An electrical method for the measurement of the thermal and electrical conductivity of reduced graphene oxide nanostructures
    www.ltnt.ethz.ch/publications/Journal/pubimg/2009_Schwamb.pdf

    The electronic properties of graphene
    onnes.ph.man.ac.uk/nano/Publications/RMP_2009.pdf

    Etching of Graphene Devices with a Helium Ion Beam
    marcuslab.harvard.edu/papers/LemmeHIM_2009_ACSNano.pdf

    Fabrication of graphene nanogap with crystallographically matching edges and its electron emission properties
    www3.ntu.edu.sg/home/yuting/papers/APL-Graphene%20FE.pdf

    Field Emission of Single-Layer Graphene Films Prepared by Electrophoretic Deposition
    carbon.imr.ac.cn/file/Journal/2009/1249017676305.pdf

    Graphene Nanoribbons Obtained by Electrically Unwrapping Carbon Nanotubes
    http://www.physics.berkeley.edu/research/zettl/pdf/373.ACSNano-Kim.pdf

    Graphene on various substrates
    epub.uni-regensburg.de/13946/

    Graphene Times (this site works like a news feed; it links to the latest articles about graphene on a variety of Websites)
    www.graphenetimes.com

    Graphene transistor breaks new record
    physicsworld.com/cws/article/news/41643

    Graphene Transistors that Can Work at Blistering Speeds
    www.technologyreview.com/computing/24482/

    Epitaxial Graphene Films on SiC: Growth,Characterization, and Devices
    smartech.gatech.edu/handle/1853/24670

    A Hybrid Material of Graphene and Poly (3,4-ethyldioxythiophene) with High Conductivity, Flexibility and Transparency
    www.thenanoresearch.com/files/343_ESM.pdf

    Infrared Microscopy of Joule Heating in Graphene Field Effect Transistors
    poplab.ece.illinois.edu/pdfs/BaeOngEstradaPop_IEEENANO_AsPublished_2009.pdf

    Organic Photovoltaic Devices Based on a Novel Acceptor Material: Graphene
    nanocenter.nankai.edu.cn/script/nanocenter/paper/adv2008-LZF.pdf

    Practical Chemical Sensors from Chemically Derived Graphene
    yylab.seas.ucla.edu/papers/nn800593m.lowlink.pdf_v03.pdf

    Supercapacitor Devices Based on Graphene Materials
    nanocenter.nankai.edu.cn/script/nanocenter/paper/2009/WY_2009_jp902214f.pdf

    Synthesis of graphene-based nanosheets via chemical reduction of exfoliated graphite oxide
    bucky-central.me.utexas.edu/RuoffsPDFs/Synthesis_of_graphene-based_nanosheets_via_chemical_reduction_of_exfoliated_graphite_oxide.pdf

    Transport properties of graphene in the high-current limit
    arxiv.org/ftp/arxiv/papers/0906/0906.0188.pdf

    Tunable Graphene dc Superconducting Quantum Interference Device
    www.physics.berkeley.edu/research/zettl/pdf/358.NanoLett.9-Girit.pdf

    Ultra-large single-layer graphene obtained from solution chemical reduction and its electrical properties
    idv.sinica.edu.tw/lanceli/Paper%20PDF/Ultra-large%20single-layer%20graphene%20obtained%20from%20solution%20chemical%20reduction%20and%20
    its%20electrical%20properties.pdf


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